Jump to main content
Jump to site search

Issue 24, 2015
Previous Article Next Article

Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Author affiliations

Abstract

Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.

Graphical abstract: Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Back to tab navigation

Supplementary files

Article information


Submitted
15 Jan 2015
Accepted
13 Feb 2015
First published
23 Feb 2015

Chem. Commun., 2015,51, 5044-5047
Article type
Communication
Author version available

Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

M. Sidera and S. P. Fletcher, Chem. Commun., 2015, 51, 5044
DOI: 10.1039/C5CC00421G

Social activity

Search articles by author

Spotlight

Advertisements