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Issue 22, 2015
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A reversible two-electron redox system involving a divalent lead species

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Abstract

Reduction of THF-stabilized plumbacyclopentadienylidene with lithium afforded dilithioplumbole. On the other hand, oxidation of the dilithioplumbole provided the starting plumbacyclopentadienylidene. This is the unprecedented example of a reversible interconversion between group 14 M(II) and its dianionic species bearing organic substituents.

Graphical abstract: A reversible two-electron redox system involving a divalent lead species

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Publication details

The article was received on 10 Dec 2014, accepted on 06 Feb 2015 and first published on 10 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC09856K
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Chem. Commun., 2015,51, 4674-4676

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    A reversible two-electron redox system involving a divalent lead species

    M. Saito, M. Nakada, T. Kuwabara and M. Minoura, Chem. Commun., 2015, 51, 4674
    DOI: 10.1039/C4CC09856K

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