Issue 30, 2015
From the journal:

Chemical Communications

Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker†

Daniel J. Clingerman,a   William Morris,a   Joseph E. Mondloch,a   Robert D. Kennedy,a   Amy A. Sarjeant,a   Charlotte Stern,a   Joseph T. Hupp,a   Omar K. Farhaab  and  Chad A. Mirkin*a  

* Corresponding authors

a Department of Chemistry and International Institute for Nanotechnology, Northwestern University, Evanston, IL, USA
E-mail: chadnano@northwestern.edu
Fax: +1 847 467 5123
Tel: +1 847 467 7302

b Department of Chemistry, Faculty of Science, King Abdulaziz, Jeddah, Saudi Arabia

Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal–organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g−1.

Graphical abstract: Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

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Article information

DOI
https://doi.org/10.1039/C4CC09212K
Article type
Communication
Submitted
18 Nov 2014
Accepted
22 Feb 2015
First published
13 Mar 2015

Chem. Commun., 2015,51, 6521-6523

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Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

D. J. Clingerman, W. Morris, J. E. Mondloch, R. D. Kennedy, A. A. Sarjeant, C. Stern, J. T. Hupp, O. K. Farha and C. A. Mirkin, Chem. Commun., 2015, 51, 6521 DOI: 10.1039/C4CC09212K

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