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Issue 25, 2015
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Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)

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Abstract

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

Graphical abstract: Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)

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Publication details

The article was received on 02 Nov 2014, accepted on 16 Dec 2014 and first published on 16 Dec 2014


Article type: Communication
DOI: 10.1039/C4CC08718F
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Chem. Commun., 2015,51, 5402-5405
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    Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

    S. D. Woodall, A. N. Swinburne, N. lal Banik, A. Kerridge, P. Di Pietro, C. Adam, P. Kaden and L. S. Natrajan, Chem. Commun., 2015, 51, 5402
    DOI: 10.1039/C4CC08718F

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