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Issue 9, 2015
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Thiophene-fused bowl-shaped polycyclic aromatics with a dibenzo[a,g]corannulene core for organic field-effect transistors

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Abstract

For the first time, electron-rich thiophene units were fused into the skeleton of corannulene to extend π-surfaces and tune arrangement in single crystals. Two isomeric butterfly-like thiophene-fused dibenzo[a,g]corannulenes (3 and 5) were synthesized. Isomer 3 showed p-type transport properties, with a hole mobility of 0.06 cm2 V−1 s−1.

Graphical abstract: Thiophene-fused bowl-shaped polycyclic aromatics with a dibenzo[a,g]corannulene core for organic field-effect transistors

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Article information


Submitted
27 Oct 2014
Accepted
03 Dec 2014
First published
04 Dec 2014

Chem. Commun., 2015,51, 1681-1684
Article type
Communication
Author version available

Thiophene-fused bowl-shaped polycyclic aromatics with a dibenzo[a,g]corannulene core for organic field-effect transistors

R. Lu, Y. Zhou, X. Yan, K. Shi, Y. Zheng, M. Luo, X. Wang, J. Pei, H. Xia, L. Zoppi, K. K. Baldridge, J. S. Siegel and X. Cao, Chem. Commun., 2015, 51, 1681
DOI: 10.1039/C4CC08451A

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