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Issue 4, 2015
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Formation of a quasi-solid structure by intercalated noble gas atoms in pores of CuI-MFU-4l metal–organic framework

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Abstract

The primary adsorption sites for Kr and Xe within the large-pore metal–organic framework CuI-MFU-4l have been investigated by high-resolution synchrotron powder diffraction, revealing an enormous number of adsorption sites: in total, 10 crystallographically different positions for Xe and 8 positions for Kr were localized, the first five of which are located near metal atoms and the organic linker, and the remaining sites form a second adsorption layer in the pores.

Graphical abstract: Formation of a quasi-solid structure by intercalated noble gas atoms in pores of CuI-MFU-4l metal–organic framework

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Publication details

The article was received on 24 Sep 2014, accepted on 11 Nov 2014 and first published on 11 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC07554D
Chem. Commun., 2015,51, 714-717
  • Open access: Creative Commons BY-NC license
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    Formation of a quasi-solid structure by intercalated noble gas atoms in pores of CuI-MFU-4l metal–organic framework

    O. V. Magdysyuk, D. Denysenko, I. Weinrauch, D. Volkmer, M. Hirscher and R. E. Dinnebier, Chem. Commun., 2015, 51, 714
    DOI: 10.1039/C4CC07554D

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