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Issue 24, 2015
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Neutral binuclear rare-earth metal complexes with four μ2-bridging hydrides

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Abstract

The first neutral rare-earth metal dinuclear dihydrido complexes [(NPNPN)LnH2]2 (2-Ln; Ln = Y, Lu; NPNPN: N[Ph2PNC6H3(iPr)2]2) bearing μ2-bridging hydride ligands have been synthesized. In the presence of THF, 2-Y undergoes intramolecular activation of the sp2 C–H bond to form dinuclear aryl–hydride complex 3-Y containing three μ2-bridging hydride ligands.

Graphical abstract: Neutral binuclear rare-earth metal complexes with four μ2-bridging hydrides

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Publication details

The article was received on 14 Sep 2014, accepted on 26 Jan 2015 and first published on 11 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC07262F
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Chem. Commun., 2015,51, 5063-5065

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    Neutral binuclear rare-earth metal complexes with four μ2-bridging hydrides

    W. Rong, D. He, M. Wang, Z. Mou, J. Cheng, C. Yao, S. Li, A. A. Trifonov, D. M. Lyubov and D. Cui, Chem. Commun., 2015, 51, 5063
    DOI: 10.1039/C4CC07262F

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