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Issue 25, 2015
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A radical spin on viologen polymers: organic spin crossover materials in water

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Abstract

A polymer containing viologen radical cation monomer units is shown to reversibly switch between paramagnetic and diamagnetic states via non-covalent host–guest interactions or temperature control in water. Cycling between diamagnetic and paramagnetic forms is accompanied by changes in optical and magnetic properties.

Graphical abstract: A radical spin on viologen polymers: organic spin crossover materials in water

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Supplementary files

Article information


Submitted
10 Sep 2014
Accepted
23 Sep 2014
First published
24 Sep 2014

Chem. Commun., 2015,51, 5516-5519
Article type
Communication
Author version available

A radical spin on viologen polymers: organic spin crossover materials in water

M. J. Juetten, A. T. Buck and A. H. Winter, Chem. Commun., 2015, 51, 5516 DOI: 10.1039/C4CC07119K

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