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Issue 21, 2014
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Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials†

Xiaoxia Lin,ab   Fangfang Zhang,*a   Shilie Pan,*a   Hongwei Yu,ab   Fangyuan Zhang,abc   Xiaoyu Dong,ab   Shujuan Han,a   Lingyun Dong,ab   Chunyan Baiab  and  Zheng Wangab  
Author affiliations

* Corresponding authors

a Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: ffzhang@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn
Fax: +(86)-991-3838957
Tel: +(86)-991-3674558

b University of Chinese Academy of Sciences, Beijing 100049, China

c College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Abstract

Based on the combination of two different anionic groups (SiO4 and BO3) and the utility of a XBa6 (X = Cl, Br) polar template, two new salt-inclusion compounds, Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br) have been successfully synthesized by the high-temperature solution method for the first time. They are isostructural and their structures feature the ∞3[Ba4(BO3)3(SiO4)] framework with 1D channels along the c axis, in which resided the polar ∞1[Ba3X] chains. It is worth noting that they are the first alkaline-earth metal borosilicate halides to be used as nonlinear optical (NLO) materials. The second harmonic generation (SHG) measurements show that they have SHG responses similar to that of KH2PO4 (KDP) and are type-I phase-matchable. In addition, they melt congruently and exhibit a wide transparent region with the UV cut-off edge below 190 nm. These properties make Ba4(BO3)3(SiO4)·Ba3X potential deep UV NLO materials.

Graphical abstract: Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

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Article information

https://doi.org/10.1039/C4TC00079J
Submitted
13 Jan 2014
Accepted
11 Mar 2014
First published
12 Mar 2014
J. Mater. Chem. C, 2014,2, 4257-4264
Article type
Paper
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Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

X. Lin, F. Zhang, S. Pan, H. Yu, F. Zhang, X. Dong, S. Han, L. Dong, C. Bai and Z. Wang, J. Mater. Chem. C, 2014, 2, 4257
DOI: 10.1039/C4TC00079J

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