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Issue 34, 2014
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Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

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Abstract

A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitro monomers. Azo-POF-2 exhibits the highest CO2/N2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers.

Graphical abstract: Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

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Supplementary files

Article information


Submitted
14 Jun 2014
Accepted
26 Jun 2014
First published
02 Jul 2014

J. Mater. Chem. A, 2014,2, 13831-13834
Article type
Communication
Author version available

Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

J. Lu and J. Zhang, J. Mater. Chem. A, 2014, 2, 13831
DOI: 10.1039/C4TA03015J

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