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Issue 6, 2014
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Fe3S4 (greigite) formation by vapor–solid reaction

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Fe3S4 (greigite), a ferrimagnetic compound widely encountered in nature and of increasing technical interest, is prepared by vapor–solid interaction. This is done in a laterally resolving ultrahigh vacuum multi-method instrument, which not only allows in situ analysis of the reaction product without influence of the environment but also follows its evolution during the reaction. The physical method employed here avoids formation of unwanted reaction products that are produced by the usual wet chemical synthesis methods. The resulting greigite crystals exhibit complex intergrowth, faceting and nanoparticle substructure and are somewhat distorted from a pure cubic symmetry. A new Curie temperature above 450 °C is established.

Graphical abstract: Fe3S4 (greigite) formation by vapor–solid reaction

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Publication details

The article was received on 27 Sep 2013, accepted on 23 Nov 2013 and first published on 25 Nov 2013

Article type: Paper
DOI: 10.1039/C3TA13909C
Citation: J. Mater. Chem. A, 2014,2, 1903-1913

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    Fe3S4 (greigite) formation by vapor–solid reaction

    E. Bauer, K. L. Man, A. Pavlovska, A. Locatelli, T. O. Menteş, M. A. Niño and M. S. Altman, J. Mater. Chem. A, 2014, 2, 1903
    DOI: 10.1039/C3TA13909C

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