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Issue 29, 2014
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Comparison between generations of foams and single vertical films – single and mixed surfactant systems

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Abstract

The purpose of this article is to compare experiments carried out with single vertical foam films and with foams. We focus on the generation of films and foams and measure (i) the quantity of water entrained and (ii) the stability of the systems. The surfactants we used are C12E6, β-C12G2 and their 1 : 1 mixture because those systems are very well characterised in the literature and are known to stabilise foams with very different properties. We show that the quantity of water uptake in foams and single vertical films scales in the same way with the velocity of generation. However, the different surfactant solutions have different foamabilities, whereas the films they stabilise have exactly the same thickness. Moreover, the foamability of a C12E6 solution is much lower than that of a β-C12G2 solution or of a solution of the 1 : 1 mixture. This is due to the rapid rupture of the C12E6 foam films during foam generation. Surprisingly, the isolated films have exactly the same lifetime for all the surfactant solutions. We conclude that, though drawing a correlation between films and foams is tempting, the results obtained do not allow correlating of film and foam stability during the generation process. The only difference we observed between the single films stabilised by the different solutions is the stability of their respective black films. We thus suggest that the stability of black films during foam generation plays an important role which should be explored further in future work.

Graphical abstract: Comparison between generations of foams and single vertical films – single and mixed surfactant systems

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Supplementary files

Article information


Submitted
11 Feb 2014
Accepted
01 Apr 2014
First published
03 Apr 2014

Soft Matter, 2014,10, 5280-5288
Article type
Paper

Comparison between generations of foams and single vertical films – single and mixed surfactant systems

L. Saulnier, J. Boos, C. Stubenrauch and E. Rio, Soft Matter, 2014, 10, 5280
DOI: 10.1039/C4SM00326H

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