Issue 90, 2014

Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups

Abstract

An inexpensive protocol for the conversion of –C6H4R into –COOH groups using Co(II)–Oxone mixture as the catalytic system is described. A series of substrates containing substituted and non-substituted phenyl groups could be selectively converted into carboxylic acids. Initial mechanistic data have been provided.

Graphical abstract: Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups

Supplementary files

Article information

Article type
Communication
Submitted
25 Aug 2014
Accepted
25 Sep 2014
First published
25 Sep 2014

RSC Adv., 2014,4, 49395-49399

Author version available

Co(II), a catalyst for selective conversion of phenyl rings to carboxylic acid groups

S. B. Sinha, J. Campos, G. W. Brudvig and R. H. Crabtree, RSC Adv., 2014, 4, 49395 DOI: 10.1039/C4RA10510A

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