Issue 106, 2014

End-group differentiating ozonolysis of furocoumarins

Abstract

Ozonolysis of furocoumarins followed by reductive work-up yields not only common symmetrical dialdehydes, but also o-formylumbelliferones with moderate-to-high yields. Simultaneous formation of both products accounts for the transformation of carbonyl oxides – products of primary ozonide ring opening.

Graphical abstract: End-group differentiating ozonolysis of furocoumarins

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug 2014
Accepted
10 Nov 2014
First published
10 Nov 2014

RSC Adv., 2014,4, 61277-61280

Author version available

End-group differentiating ozonolysis of furocoumarins

M. V. Malakhov, M. A. Dubinnyi, N. V. Vlasova, V. G. Zgoda, R. G. Efremov and I. A. Boldyrev, RSC Adv., 2014, 4, 61277 DOI: 10.1039/C4RA08106D

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