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The hydrothermal reaction of 4,4′-dicarboxybiphenyl sulfone and dysprosium(III) nitrate in the presence of L-histidine yielded the first 2D → 2D polyrotaxane lanthanide–organic framework, which possesses both polyrotaxane and polycatenane topology features. Magnetic investigations indicated that it is a field-induced single-molecule magnet with two-step magnetic relaxation processes.

Graphical abstract: A 2D → 2D polyrotaxane lanthanide–organic framework showing field-induced single-molecule magnet behaviour

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