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Issue 58, 2014
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Novel chiral tetramic acid-derived diols: organocatalytic facile synthesis and unique structural properties

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Abstract

Organocatalytic tandem reactions of L-phenylalanine-derived tetramic acid with aldehydes allow a one-pot and high-yielding access to a diverse range of novel chiral diols in enantiomerically pure forms. In addition, a new entry of the diols, featuring their unique structures associated with C2- and pseudo C2-symmetric chiral motifs, is reported.

Graphical abstract: Novel chiral tetramic acid-derived diols: organocatalytic facile synthesis and unique structural properties

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Publication details

The article was received on 06 Jun 2014, accepted on 01 Jul 2014 and first published on 04 Jul 2014


Article type: Communication
DOI: 10.1039/C4RA05405A
RSC Adv., 2014,4, 30775-30779

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    Novel chiral tetramic acid-derived diols: organocatalytic facile synthesis and unique structural properties

    T. Sengoku, K. Suzuki, K. Nakayama, F. Yagishita, M. Sakamoto, M. Takahashi and H. Yoda, RSC Adv., 2014, 4, 30775
    DOI: 10.1039/C4RA05405A

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