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Issue 50, 2014
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Simple procedure for vacant POM-stabilized palladium (0) nanoparticles in water: structural and dispersive effects of lacunary polyoxometalates

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Abstract

Metallic palladium nanoparticles have been generated by hydrogenation with H2 of solutions of several non organometallic PdII-derivatives of heteropolytungstates, at ambient temperature and atmospheric pressure. These nanoparticles have been characterized by various techniques: 31P NMR and Raman spectroscopy, TEM (including cryogenic techniques), DLS, EDX and XPS. The present strategy ruled out the presence of ligands and/or stabilizing agents other than the lacunary polyoxometalates (POMs) used. This allows the evaluation of the true efficiency of the different vacant POMs for the stabilization of the nanoparticles.

Graphical abstract: Simple procedure for vacant POM-stabilized palladium (0) nanoparticles in water: structural and dispersive effects of lacunary polyoxometalates

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Supplementary files

Article information


Submitted
07 Apr 2014
Accepted
30 May 2014
First published
06 Jun 2014

RSC Adv., 2014,4, 26491-26498
Article type
Paper
Author version available

Simple procedure for vacant POM-stabilized palladium (0) nanoparticles in water: structural and dispersive effects of lacunary polyoxometalates

R. Villanneau, A. Roucoux, P. Beaunier, D. Brouri and A. Proust, RSC Adv., 2014, 4, 26491
DOI: 10.1039/C4RA03104K

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