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Issue 40, 2014
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A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions

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Abstract

A new synthetic method for homopropargylic amines from alkyl azides is presented. A salient feature of this reaction is the involvement of N-unsubstituted imines as the key intermediates, which are generated from alkyl azides by Ru catalysis under photolytic conditions. Notably, this method avoids the use of a protective group strategy in the homopropargylic amine synthesis.

Graphical abstract: A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions

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Publication details

The article was received on 01 Mar 2014, accepted on 16 Apr 2014 and first published on 17 Apr 2014


Article type: Communication
DOI: 10.1039/C4RA02941K
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RSC Adv., 2014,4, 20632-20635

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    A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions

    W. Jeong, J. H. Lee, J. Kim, W. J. Lee, J. Seong, J. Park and Y. H. Rhee, RSC Adv., 2014, 4, 20632
    DOI: 10.1039/C4RA02941K

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