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Issue 26, 2014
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A new mesomeso directly-linked corrole–porphyrin–corrole hybrid: synthesis and photophysical properties

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Abstract

A first example of a directly-linked corrole–porphyrin–corrole (Cor–Por–Cor) triad has been targeted and synthesized. The new hybrid has been fully characterized by 1H NMR, 19F NMR and 2D NMR spectroscopy. The fluorescence quantum yield of the triad is three times higher than that of mesomeso directly linked porphyrin trimers. All the three chromophores assume a near orthogonal geometry with respect to the neighbour.

Graphical abstract: A new meso–meso directly-linked corrole–porphyrin–corrole hybrid: synthesis and photophysical properties

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Supplementary files

Article information


Submitted
09 Jan 2014
Accepted
28 Feb 2014
First published
28 Feb 2014

RSC Adv., 2014,4, 13669-13672
Article type
Communication
Author version available

A new mesomeso directly-linked corrole–porphyrin–corrole hybrid: synthesis and photophysical properties

M. Murugavel, R. V. R. Reddy and J. Sankar, RSC Adv., 2014, 4, 13669
DOI: 10.1039/C4RA01229A

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