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Issue 25, 2014
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Rare nuclearities in Ni(ii) cluster chemistry: a Ni11 cage from the first use of N-salicylidene-2-amino-5-chlorobenzoic acid in metal cluster chemistry

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Abstract

The reaction between N-salicylidene-2-amino-5-chlorobenzoic acid (sacbH2), ButCH2CO2H, and Ni(ClO4)2·6H2O leads to a new Ni11 cluster comprising Ni4 squares and Ni3 triangles; the compound is antiferromagnetically-coupled with an S = 1 spin ground state and low-lying excited states populated even at the lowest accessible temperatures.

Graphical abstract: Rare nuclearities in Ni(ii) cluster chemistry: a Ni11 cage from the first use of N-salicylidene-2-amino-5-chlorobenzoic acid in metal cluster chemistry

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Article information


Submitted
24 Jan 2014
Accepted
24 Feb 2014
First published
24 Feb 2014

RSC Adv., 2014,4, 12680-12684
Article type
Communication
Author version available

Rare nuclearities in Ni(II) cluster chemistry: a Ni11 cage from the first use of N-salicylidene-2-amino-5-chlorobenzoic acid in metal cluster chemistry

A. A. Athanasopoulou, C. P. Raptopoulou, A. Escuer and T. C. Stamatatos, RSC Adv., 2014, 4, 12680
DOI: 10.1039/C4RA00738G

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