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Issue 22, 2014
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Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand

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Abstract

The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) varies from 259 K when X = BPh4 to 277 K when X = Br, at 10 mM concentrations in an acetone–water solvent mixture.

Graphical abstract: Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand

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Publication details

The article was received on 09 Jan 2014, accepted on 11 Feb 2014 and first published on 12 Feb 2014


Article type: Communication
DOI: 10.1039/C4RA00230J
RSC Adv., 2014,4, 11240-11243

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    Anion-dependent spin crossover in solution for an iron(II) complex of a 1H-pyrazolyl ligand

    S. A. Barrett and M. A. Halcrow, RSC Adv., 2014, 4, 11240
    DOI: 10.1039/C4RA00230J

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