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Issue 55, 2014
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Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba3Cu4SbS6OH, BaCuSbS3 and BaCu2S2†

Zhimin Ma,a   Fan Weng,b   Qiuran Wang,b   Qun Tang,b   Ganghua Zhang,c   Chong Zheng,d   Ray P. S. Hana  and  Fuqiang Huang*abc  
Author affiliations

* Corresponding authors

a Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China
E-mail: huangfq@pku.edu.cn
Fax: +86-10-62767628
Tel: +86-10-62758225

b State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

c State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

d Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115, USA

Abstract

For the first time, alkaline earth metal multinary chalcogenides Ba3Cu4SbS6OH (1), BaCuSbS3 (2) and BaCu2S2 (3) were synthesized via hydrothermal methods at low temperatures. The structures of these three compounds contain three-dimensional channeled frameworks that are constructed by different types of Cu/S chains.

Graphical abstract: Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba3Cu4SbS6OH, BaCuSbS3 and BaCu2S2

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Article information

https://doi.org/10.1039/C3RA46878J
Submitted
20 Nov 2013
Accepted
11 Jun 2014
First published
12 Jun 2014
RSC Adv., 2014,4, 28937-28940
Article type
Communication
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Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba3Cu4SbS6OH, BaCuSbS3 and BaCu2S2

Z. Ma, F. Weng, Q. Wang, Q. Tang, G. Zhang, C. Zheng, R. P. S. Han and F. Huang, RSC Adv., 2014, 4, 28937
DOI: 10.1039/C3RA46878J

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