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The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ring-opening.

Graphical abstract: Intermolecular reactions of gold(i)-carbenes with furans by related mechanisms

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