Issue 10, 2014
From the journal:

Polymer Chemistry

Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones†

Lidia Jasinska-Walc,*abc   Michael Ryan Hansen,de   Dmytro Dudenko,df   Artur Rozanski,g   Miloud Bouyahyi,c   Manfred Wagner,d   Robert Grafd  and  Robbert Duchateau*ac  

* Corresponding authors

a Department of Polymer Chemistry, Eindhoven University of Technology, Eindhoven, The Netherlands
E-mail: R. Duchateau@tue.nl, L.Jasinska@tue.nl

b Department of Polymer Technology, Chemical Faculty, Gdansk University of Technology, Gdansk, Poland

c SABIC Europe B.V., Geleen, The Netherlands

d Max Planck Institute for Polymer Research, Mainz, Germany

e Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, Aarhus C, Denmark

f University of Warwick, Department of Physics, Coventry, UK

g Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Lodz, Poland

Abstract

A new approach towards polyolefin-like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance and monomer reactivity determines whether random or block copolymers are formed.

Graphical abstract: Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones

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Article information

DOI
https://doi.org/10.1039/C3PY01754K
Article type
Communication
Submitted
22 Dec 2013
Accepted
03 Feb 2014
First published
04 Feb 2014

Polym. Chem., 2014,5, 3306-3310

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Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones

L. Jasinska-Walc, M. R. Hansen, D. Dudenko, A. Rozanski, M. Bouyahyi, M. Wagner, R. Graf and R. Duchateau, Polym. Chem., 2014, 5, 3306 DOI: 10.1039/C3PY01754K

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