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Issue 41, 2017
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Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

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Abstract

A designed N,N′-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

Graphical abstract: Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

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Article information


Submitted
02 Sep 2017
Accepted
05 Oct 2017
First published
05 Oct 2017

Org. Biomol. Chem., 2017,15, 8810-8819
Article type
Paper

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

K. J. Emery, T. Tuttle and J. A. Murphy, Org. Biomol. Chem., 2017, 15, 8810
DOI: 10.1039/C7OB02209C

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