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Abstract | Cited by

The preparation of an advanced intermediate on route towards the synthesis of tedanolide C is reported here. It is based on the coupling of two fragments of similar size and complexity, which in turn are prepared by highly stereoselective substrate-controlled titanium-mediated aldol reactions from chiral ketones.

Graphical abstract: Studies towards the synthesis of tedanolide C. Construction of the C13-epi C1–C15 fragment

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