Issue 36, 2014

A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

Abstract

A tandem one-pot method for the direct synthesis of polysubstituted triphenylene 2,3-dicarboxylic esters with different substitution patterns was developed by enyne metathesis of diarylacetylene, followed by Diels–Alder, aromatization and a cyclization cascade.

Graphical abstract: A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2014
Accepted
29 Jul 2014
First published
29 Jul 2014

Org. Biomol. Chem., 2014,12, 6977-6981

Author version available

A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

C. Feng, X. Tian, J. Zhou, S. Xiang, W. Yu, B. Wang, P. Hu, C. Redshaw and K. Zhao, Org. Biomol. Chem., 2014, 12, 6977 DOI: 10.1039/C4OB01503G

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