A palladium-catalyzed cascade reaction of N–H insertion (NHI) and oxidative dehydrogenative aromatization (ODA) has been developed, which affords a straightforward and efficient way to access the carbazole precursors (2-arylamino-phenols) as well as to prepare 2-alkylamino-phenols from non-aromatic substrates.
D. Ding, X. Lv, J. Li, L. Qiu, G. Xu and J. Sun, Org. Biomol. Chem., 2014, 12, 4084 DOI: 10.1039/C4OB00652F
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