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A copper-mediated trifluoromethylation of propargyl acetates with S-(trifluoromethyl)diphenylsulfonium triflate leading to trifluoromethylated allenes in moderate to excellent yields is described.

Graphical abstract: Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes

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