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Issue 10, 2014
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Asymmetric benzoylation and Henry reaction using reusable polytopic bis(oxazoline) ligands and copper(ii)

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Abstract

Multitopic bis(oxazoline)-based chiral ligands are associated with copper to generate catalysts for the asymmetric benzoylation of meso-hydrobenzoin, the kinetic resolution of rac-hydrobenzoin and the asymmetric Henry reaction. The recycling of the catalytic systems has been studied. The recycling efficiency of the system was found to be dependent on the copper source used.

Graphical abstract: Asymmetric benzoylation and Henry reaction using reusable polytopic bis(oxazoline) ligands and copper(ii)

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Article information


Submitted
24 Apr 2014
Accepted
28 Jul 2014
First published
18 Aug 2014

New J. Chem., 2014,38, 4748-4753
Article type
Paper
Author version available

Asymmetric benzoylation and Henry reaction using reusable polytopic bis(oxazoline) ligands and copper(II)

M. Torres-Werlé, A. Nano, A. Maisse-François and S. Bellemin-Laponnaz, New J. Chem., 2014, 38, 4748
DOI: 10.1039/C4NJ00653D

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