Designing ionic liquids for absorptive cooling

Abstract

A computational methodology for designing ionic liquids (ILs) with an enhanced water absorption capacity to be used in absorption-refrigeration systems is presented here. It is based on increasing the hydrogen bond (HB)-acceptor ability of the anion and combining it with a cation that presents a weak cation–anion interaction. Employing this strategy, we identified and prepared three novel dianionic ILs with an enhanced water absorption capacity, larger than LiBr.