Low band gap S,N-heteroacene-based oligothiophenes as hole-transporting and light absorbing materials for efficient perovskite-based solar cells

Abstract

Novel low band gap oligothiophenes incorporating S,N-heteropentacene central units were developed and used as hole-transport materials (HTMs) in solid-state perovskite-based solar cells. In addition to appropriate electronic energy levels, these materials show high photo-absorptivity in the low energy region, and thus can contribute to the light harvesting of the solar spectrum. Solution-processed CH₃NH₃PbI₃-based devices using these HTMs achieved power conversion efficiencies of 9.5–10.5% in comparison with 7.6% obtained by reference devices without HTMs. Photoinduced absorption spectroscopy gave further insight into the charge transfer behavior between photoexcited perovskites and the HTMs.