Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.
J. McKinven, G. S. Nichol and P. L. Arnold, Dalton Trans., 2014, 43, 17416 DOI: 10.1039/C4DT02995J
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