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Issue 11, 2015
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Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(III) complexes

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Abstract

Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(III) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.

Graphical abstract: Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes

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Publication details

The article was received on 26 Sep 2014, accepted on 07 Nov 2014 and first published on 07 Nov 2014


Article type: Paper
DOI: 10.1039/C4DT02971B
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Citation: Dalton Trans., 2015,44, 4910-4917

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    Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(III) complexes

    D. Lawson, A. Barge, E. Terreno, D. Parker, S. Aime and M. Botta, Dalton Trans., 2015, 44, 4910
    DOI: 10.1039/C4DT02971B

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