Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect

Abstract

Two Cu^II-based MOFs have been constructed by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect. Compound 1 is a 3D structure and represents a cds topology, while compound 2 displays a rare structure built by three distinct {Cu₄} clusters as SBUs. Moreover, the magnetic properties of 2 have been thoroughly investigated.