Issue 33, 2014
From the journal:

Dalton Transactions

High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism†

Cheng-Liang Xiao,a   Qun-Yan Wu,a   Lei Mei,a   Li-Yong Yuan,a   Cong-Zhi Wang,a   Yu-Liang Zhao,a   Zhi-Fang Chai*ab  and  Wei-Qun Shi*a  

* Corresponding authors

a Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory For Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
E-mail: shiwq@ihep.ac.cn
Fax: +86-10-88235294
Tel: +86-10-88233968

b School of Radiological & Interdisciplinary Sciences, Soochow University, Suzhou 215123, China
E-mail: zfchai@suda.edu.cn

Abstract

A preorganized tetradentate phenanthroline-derived amide ligand, N,N′-diethyl-N,N′-ditolyl-2,9-dicarboxamide-1,10-phenanthroline (Et-Tol-DAPhen), was found to show high selectivity towards small copper ions, which might be due to the change of the coordination mechanism from tetradentate to terdentate mode.

Graphical abstract: High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

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Article information

DOI
https://doi.org/10.1039/C4DT01489H
Article type
Communication
Submitted
21 May 2014
Accepted
24 Jun 2014
First published
26 Jun 2014

Dalton Trans., 2014,43, 12470-12473

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High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

C. Xiao, Q. Wu, L. Mei, L. Yuan, C. Wang, Y. Zhao, Z. Chai and W. Shi, Dalton Trans., 2014, 43, 12470 DOI: 10.1039/C4DT01489H

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