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Issue 28, 2014
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Hysteretic behaviour in a vacuum deposited submonolayer of single ion magnets

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Abstract

With element-specific X-ray absorption spectroscopy and X-ray magnetic circular dichroism we have investigated submonolayer coverages of TbPc2 and DyPc2 molecules sublimated on highly ordered pyrolytic graphite. We have studied the field dependence of the magnetization of the central lanthanide ion at very low temperatures. Even in zero applied magnetic field we still observe a remanence in the magnetization. Since there are neither intermolecular coupling nor magnetic interactions with the substrate, this remanent behaviour results just from single-ion anisotropy. On the very inert surface of graphite at temperatures between 0.5 K and 2 K the spin relaxation is slow enough to observe a memory effect in the timescale of the experimental measurements.

Graphical abstract: Hysteretic behaviour in a vacuum deposited submonolayer of single ion magnets

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Supplementary files

Article information


Submitted
04 Apr 2014
Accepted
12 May 2014
First published
13 May 2014

This article is Open Access

Dalton Trans., 2014,43, 10686-10689
Article type
Communication

Hysteretic behaviour in a vacuum deposited submonolayer of single ion magnets

D. Klar, A. Candini, L. Joly, S. Klyatskaya, B. Krumme, P. Ohresser, J. Kappler, M. Ruben and H. Wende, Dalton Trans., 2014, 43, 10686
DOI: 10.1039/C4DT01005A

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