Issue 23, 2014

Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates

Abstract

A series of tripodal alcohols substituted Anderson-type polyoxometalates (POMs) including mono-substituted (compounds 1 and 2), asymmetrical bi-substituted (compound 3), and symmetrical bi-substituted ones (compounds 4 and 5) have been synthesized under hydrothermal conditions using a pre-designed step-by-step strategy, and compounds 1, 2 and 4 have been fully characterized by single-crystal X-ray diffraction, ESI-MS, and elemental analysis.

Graphical abstract: Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates

Supplementary files

Article information

Article type
Communication
Submitted
06 Jan 2014
Accepted
06 Mar 2014
First published
03 Apr 2014
This article is Open Access
Creative Commons BY license

Dalton Trans., 2014,43, 8587-8590

Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates

C. Lin, W. Chen, D. Long, L. Cronin and Y. Song, Dalton Trans., 2014, 43, 8587 DOI: 10.1039/C4DT00033A

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