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Issue 16, 2014
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A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

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Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as “polymeric ligands” to immobilise the molybdenum cluster complex.

Graphical abstract: A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

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Publication details

The article was received on 05 Nov 2013, accepted on 16 Jan 2014 and first published on 17 Jan 2014


Article type: Paper
DOI: 10.1039/C3DT53126K
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Dalton Trans., 2014,43, 6021-6025

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    A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

    O. A. Efremova, M. A. Shestopalov, N. A. Chirtsova, A. I. Smolentsev, Y. V. Mironov, N. Kitamura, K. A. Brylev and A. J. Sutherland, Dalton Trans., 2014, 43, 6021
    DOI: 10.1039/C3DT53126K

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