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Issue 4, 2014
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Solid state anion–π interactions involving polyhalides

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Abstract

The stabilization of polyhalides in the solid state with the support of electron-deficient pentafluorophenyl groups is described. Furthermore, a synthetic approach towards the sensitive tetraiodide dianion is described and ESI mass spectrometric evidence for its presence in solution is reported.

Graphical abstract: Solid state anion–π interactions involving polyhalides

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Article information


Submitted
21 Oct 2013
Accepted
01 Nov 2013
First published
04 Nov 2013

Dalton Trans., 2014,43, 1873-1880
Article type
Paper

Solid state anion–π interactions involving polyhalides

M. Giese, M. Albrecht, C. Bohnen, T. Repenko, A. Valkonen and K. Rissanen, Dalton Trans., 2014, 43, 1873
DOI: 10.1039/C3DT52960F

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