Flexible and monolithic zinc oxide bionanocomposite foams by a bacterial cellulose mediated approach for antibacterial applications

Abstract

The use of self-assembled biomacromolecules in the development of functional bionanocomposite foams is one of the best lessons learned from nature. Here, we show that monolithic, flexible and porous zinc oxide bionanocomposite foams with a hierarchical architecture can be assembled through the mediation of bacterial cellulose. The assembly is achieved by controlled hydrolysis and solvothermal crystallization using a bacterial cellulose aerogel as a template in a non-aqueous polar medium. The bionanocomposite foam with a maximum zinc oxide loading of 70 wt% is constructed of intimately packed spheres of aggregated zinc oxide nanocrystals exhibiting a BET surface area of 92 m² g⁻¹. The zinc oxide bionanocomposite foams show excellent antibacterial activity, which give them potential value as self-supporting wound dressing and water sterilization materials.