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Issue 5, 2014
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Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(ii), Cu(ii) or Ni(ii) neutral complexes as metallatectons

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Abstract

The use of compound 1 as an enantiomerically pure neutral and rigid organic linear tecton bearing two divergently oriented monodentate coordinating sites appended with two chiral centres of the same (S) configuration leads, in the presence of neutral metal complexes behaving either as a linear (Cu(hfac)2, Cu(OAc)2) or a V-shaped (HgCl2) 2-connecting node or a 4-connecting square node (NiCl2), to the formation of four homochiral 1- and 2-D coordination polymers.

Graphical abstract: Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(ii), Cu(ii) or Ni(ii) neutral complexes as metallatectons

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Article information


Submitted
10 Oct 2013
Accepted
05 Nov 2013
First published
05 Nov 2013

Dalton Trans., 2014,43, 2000-2006
Article type
Paper

Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(II), Cu(II) or Ni(II) neutral complexes as metallatectons

P. Larpent, A. Jouaiti, N. Kyritsakas and M. W. Hosseini, Dalton Trans., 2014, 43, 2000
DOI: 10.1039/C3DT52850B

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