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Issue 5, 2014
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Emissive molecular nanomagnets: introducing optical properties in triangular oximato {MnIII3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

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Abstract

The targeted replacement of acetate groups in the optically inactive [MnIII3O(O2CMe)3(mpko)3](ClO4) single-molecule magnet with their naphthalene, anthracene, and pyrene fluorescent analogues has led to three new emissive SMMs with enhanced photoluminescence properties and potential applications in the field of molecular electronics.

Graphical abstract: Emissive molecular nanomagnets: introducing optical properties in triangular oximato {MnIII3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

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Supplementary files

Article information


Submitted
26 Sep 2013
Accepted
02 Nov 2013
First published
11 Nov 2013

Dalton Trans., 2014,43, 1965-1969
Article type
Communication

Emissive molecular nanomagnets: introducing optical properties in triangular oximato {MnIII3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

D. I. Alexandropoulos, A. M. Mowson, M. Pilkington, V. Bekiari, G. Christou and T. C. Stamatatos, Dalton Trans., 2014, 43, 1965
DOI: 10.1039/C3DT52571F

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