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Issue 10, 2014
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Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

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Abstract

In most kinetic investigations of catalytic reactions, catalytic activity is a traditionally measured kinetic parameter. However, differential selectivity measurements have many advantages for mechanistic studies. This Perspective gives an overview of the basic principles and practices of mechanistic studies based on differential selectivity measurements, including the use of artificially created competitive reactions.

Graphical abstract: Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

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Publication details

The article was received on 14 Apr 2014, accepted on 29 May 2014 and first published on 29 May 2014


Article type: Perspective
DOI: 10.1039/C4CY00479E
Citation: Catal. Sci. Technol., 2014,4, 3439-3457

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    Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

    A. F. Schmidt, A. A. Kurokhtina and E. V. Larina, Catal. Sci. Technol., 2014, 4, 3439
    DOI: 10.1039/C4CY00479E

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