Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 39, 2014
Previous Article Next Article

Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

Author affiliations

Abstract

Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

Graphical abstract: Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Aug 2014, accepted on 29 Aug 2014 and first published on 29 Aug 2014


Article type: Communication
DOI: 10.1039/C4CP03758H
Citation: Phys. Chem. Chem. Phys., 2014,16, 21230-21233

  •   Request permissions

    Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

    S. McMahon, J. Rochford, Y. Halpin, J. C. Manton, E. C. Harvey, G. M. Greetham, I. P. Clark, A. D. Rooney, C. Long and M. T. Pryce, Phys. Chem. Chem. Phys., 2014, 16, 21230
    DOI: 10.1039/C4CP03758H

Search articles by author

Spotlight

Advertisements