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Issue 46, 2014
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Polyoxometalate anion–π interaction-directed assembly of a three-dimensional hydrogen-bonded supramolecular framework with nanoscale porosity

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Abstract

A rare three-dimensional hydrogen-bonded supramolecular framework composed of octahedral [Cr(H3O)3(H2O)3]6+ ions and linear π-electron-deficient N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide (DPNDI) tectons was formed in the presence of electron-rich polyoxometalates by less common noncovalent anion–π interactions, indicating that polyoxometalates dominated self-assembly with anion–π interactions.

Graphical abstract: Polyoxometalate anion–π interaction-directed assembly of a three-dimensional hydrogen-bonded supramolecular framework with nanoscale porosity

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Supplementary files

Article information


Submitted
25 Jun 2014
Accepted
07 Jul 2014
First published
23 Jul 2014

CrystEngComm, 2014,16, 10530-10533
Article type
Communication

Polyoxometalate anion–π interaction-directed assembly of a three-dimensional hydrogen-bonded supramolecular framework with nanoscale porosity

J. Liao, X. Dui, H. Zhang, X. Wu and C. Lu, CrystEngComm, 2014, 16, 10530
DOI: 10.1039/C4CE01283F

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