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Issue 22, 2014
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1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(i)/Cu(ii): Cu2I2 building block, anion influence and guest inclusions

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Abstract

The reactions of a flexible bidentate ligand 1,3-phenylene diisonicotinate (L) with Cu(I/II) salts afforded coordination polymers with varied dimensionalities and guest inclusion capabilities. Complexation of L with CuI resulted in a 2D-network with (4,4) topology and inclusion of guest molecules such as CHCl3, bromobenzene, nitrobenzene and benzonitrile. The treatment of L with Cu(PF6)2 and Cu(ClO4)2 resulted in a one-dimensional network containing M2L2 macrocycles and a 4-fold interpenetrated three dimensional network having quartz topology, respectively. The 1D-networks included CHCl3 as guests and the interpenetrated 3D-network includes tetrahedral water clusters.

Graphical abstract: 1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(i)/Cu(ii): Cu2I2 building block, anion influence and guest inclusions

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Article information


Submitted
17 Jan 2014
Accepted
05 Feb 2014
First published
05 Feb 2014

CrystEngComm, 2014,16, 4701-4705
Article type
Communication
Author version available

1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(I)/Cu(II): Cu2I2 building block, anion influence and guest inclusions

G. Mukherjee and K. Biradha, CrystEngComm, 2014, 16, 4701
DOI: 10.1039/C4CE00123K

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