Spontaneous chiral resolution of a 3D (3,12)-connected MOF with an unprecedented ttt topology consisting of cubic [Cd4(μ3-OH)4] clusters and propeller-like ligands

Shuai Yuan; Yong-Kai Deng; Wei-Min Xuan; Xing-Po Wang; Su-Na Wang; Jian-Min Dou; Di Sun

doi:10.1039/C4CE00028E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Spontaneous chiral resolution of a 3D (3,12)-connected MOF with an unprecedented ttt topology consisting of cubic [Cd₄(μ₃-OH)₄] clusters and propeller-like ligands†

Shuai Yuan,‡^a Yong-Kai Deng,‡^a Wei-Min Xuan,‡^b Xing-Po Wang,^a Su-Na Wang,^c Jian-Min Dou^c and Di Sun*^a

Author affiliations

* Corresponding authors

^a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, PR China
E-mail: dsun@sdu.edu.cn
Fax: +86 531 88364218

^b School of Chemistry, WestCHEM, University of Glasgow, Glasgow, UK

^c Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, PR China

Abstract

The enantiomers of complex 1 (1Δ and 1Λ), [Cd(tipa)(μ₃-OH)·NO₃·EtOH·DMF]_n (tipa = tris(4-(1H-imidazol-1-yl)phenyl)amine), have been obtained by spontaneous resolution upon crystallization in the absence of any enantiopure substance. Complex 1 shows an unprecedented 3D (3,12)-connected metal–organic framework with ttt topology consisting of cubic [Cd₄(μ₃-OH)₄] clusters and propeller-like ligands. The anion-exchange and iodine uptake behaviors of 1 are investigated.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4CE00028E
Article type: Communication
Submitted: 06 Jan 2014
Accepted: 07 Feb 2014
First published: 07 Feb 2014

Download Citation

CrystEngComm, 2014,16, 3829-3833

Permissions

Request permissions

Spontaneous chiral resolution of a 3D (3,12)-connected MOF with an unprecedented ttt topology consisting of cubic [Cd₄(μ₃-OH)₄] clusters and propeller-like ligands

S. Yuan, Y. Deng, W. Xuan, X. Wang, S. Wang, J. Dou and D. Sun, CrystEngComm, 2014, 16, 3829 DOI: 10.1039/C4CE00028E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm