Issue 7, 2014
From the journal:

CrystEngComm

Absolute helicity induction: chiral information transfer from metal centre to the framework†

Huabin Zhang,ab   Ping Lin,a   Xiaochen Shan,ab   Liwei Hanab  and  Shaowu Du*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, PR China
E-mail: swdu@fjirsm.ac.cn
Fax: +86 591 83709470

b Graduate University of Chinese Academy of Sciences, Beijing 100039, PR China

Abstract

Pseudo-achiral metal-centre driven spontaneous resolution occurred simultaneously in the formation of two Δ- and Λ-isomers of [CdBa(OBA)2(DMF)(CH3OH)(H2O)]·H2O (H2OBA = 4,4′-oxybis(benzoic acid)), which illustrated a clear relationship between chirality and helicity: the absolute sense of a double-helix made of achiral components is induced by metal centres in the two enantiomeric forms.

Graphical abstract: Absolute helicity induction: chiral information transfer from metal centre to the framework

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Article information

DOI
https://doi.org/10.1039/C3CE42157K
Article type
Communication
Submitted
24 Oct 2013
Accepted
18 Nov 2013
First published
06 Jan 2014

CrystEngComm, 2014,16, 1245-1248

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Absolute helicity induction: chiral information transfer from metal centre to the framework

H. Zhang, P. Lin, X. Shan, L. Han and S. Du, CrystEngComm, 2014, 16, 1245 DOI: 10.1039/C3CE42157K

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