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Issue 1, 2014
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Synthesis of a Co(ii)–imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

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Abstract

A Co(II)–imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.

Graphical abstract: Synthesis of a Co(ii)–imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

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Publication details

The article was received on 08 Oct 2013, accepted on 23 Oct 2013 and first published on 25 Oct 2013


Article type: Communication
DOI: 10.1039/C3CE42040J
CrystEngComm, 2014,16, 39-42

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    Synthesis of a Co(II)–imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

    S. S. Mondal, A. Bhunia, S. Demeshko, A. Kelling, U. Schilde, C. Janiak and H. Holdt, CrystEngComm, 2014, 16, 39
    DOI: 10.1039/C3CE42040J

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